Group Publications
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175. Heavy-Atom Kinetic Isotope Effects: Primary Interest or Zero Point? Harvey J. A. Dale, Andrew G. Leach and Guy C. Lloyd-Jones* |
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174. Controlled Synthesis of Well-Defined Polyaminoboranes on Scale Using a Robust and Efficient Catalyst Claire N. Brodie, Timothy M. Boyd, Lia Sotorrios, David E. Ryan, Eimear Magee, Steven Hubbard, James S. Town, Guy C. Lloyd-Jones, David M. Haddleton,* Stuart A. Macgregor,* and Andrew S. Weller* |
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173. Glossary of Terms used in Physical Organic Chemistry Charles Perrin,* Alessandro Bagno, Silivia Braslavsky, Pedro Fernandes, Guy Lloyd-Jones, Herbert Mayr, Joseph Murdoch, Murdoch, Leo Radom, Zvi Rappoport, Marie-Françoise Ruasse, Hans-Ulrich Siehl, Thomas Tidwell, Einar Uggerud, and Ian Williams Pure Appl. Chem., 94, in press, 2021 IUPAC Recommendations 2022 |
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172. Protodeboronation of (Hetero)Arylboronic Esters: Direct versus Pre-hydrolytic Pathways and Self/Auto-Catalysis Hannah L. D. Hayes, Ran Wei, Michele Assante, Katherine J. Geogheghan, Na Jin, Simone Tomasi, Gary Noonan, Andrew G. Leach and Guy C. Lloyd-Jones* |
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171. FLIPS – Rapid Estimation of T1 for Quantitative NMR Ran Wei, Claire L. Dickson, Dušan Uhrín, and Guy C. Lloyd-Jones* |
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170. Stopped-Flow 19F NMR Spectroscopic Analysis of a Protodeboronation Proceeding at the Sub-Second Time-Scale Ran Wei, Andrew M. R. Hall, Richard Behrens, Mark S. Pritchard, Edward J. King, and Guy C. Lloyd-Jones* |
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169. Mechanism of Anion-Catalyzed C-H Silylation using TMSCF3: Kinetically-Controlled CF3-anionoid Partitioning as a Key Parameter Andrés García-Domínguez, Pedro H. Helou de Oliveira, Gilian T. Thomas, Arnau R. Sugranyes and Guy C. Lloyd-Jones* |
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168. Systematic Evaluation of 1,2-Migratory Aptitude in Alkylidene Carbenes Harvey J. A. Dale, Chris Nottingham, Carl Poree and Guy C. Lloyd-Jones* |
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167. Mechanistic Investigation of Rh(I)-Catalysed Asymmetric Suzuki- Miyaura Coupling with Racemic Allyl Halides Lucy van Dijk, Ruchuta Ardkhean, Mireia Sidera, Sedef Karabiyikoglu, Özlem Sari, Timothy D. W. Claridge,* Guy C. Lloyd-Jones,* Robert S. Paton* and Stephen P. Fletcher* |
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166. CO cleavage via InIII alkoxide intermediates: In situ 13C NMR analysis of the mechanism of an enantioselective in-mediated cyclopropanation reaction Jennifer L. Slaughter and Guy C. Lloyd-Jones*
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165. Difluorocarbene Generation from TMSCF3: Kinetics and Mechanism of NaI-Mediated and Si-Induced Anionic Chain Reactions Andrés García-Domínguez, Thomas H. West, Johann J. Primozic, Katie M. Grant, Craig P. Johnston, Grant G. Cumming, Andrew G. Leach and Guy C. Lloyd-Jones* J. Am. Chem. Soc., 142, 14649–14663, 2020 Highlighted in JACS Spotlights "Mediating Reagents Bridge the Gap for CF2 Transfer"
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164. Kinetic Analysis of Domino Catalysis: a Case Study on Gold-Catalyzed Arylation Liam T Ball, Tom Corrie, Alex Cresswell, and Guy C. Lloyd-Jones ACS Catal., 10, 10420–10426, 2020
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163. Unexpected Nickel Complex Speciation Unlocks Alternative Pathways for the Reactions of Alkyl Halides with dppf-Nickel(0) Megan Greaves, Thomas O. Ronson, Guy C. Lloyd-Jones, Feliu Maseras, Stephen Sproules and David J. Nelson ACS Catal., 10, 10717–10725, 2020
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162. Amine-Borane Dehydropolymerization using Rh-based Pre-Catalysts: Resting State Chain-Control and Efficient Polymer Synthesis David E. Ryan, Kori A. Andrea, James J. Race, Timothy M. Boyd, Guy C. Lloyd–Jones, and Andrew S. Weller* ACS Catal., 10, 7443–7448, 2020
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161. Suzuki–Miyaura Cross‐Coupling Alexander B. Pagett and Guy C. Lloyd-Jones* Organic Reactions, Volume 100, 2019
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160. Kinetics and Mechanism of the Arase-Hoshi R2BH-Catalyzed Alkyne Hydroboration: Alkenylboronate generation via B-H/C-B Metathesis Eduardo Nieto-Sepulveda, Andrew D. Bage, Louise A. Evans, Thomas A. Hunt, Andrew G. Leach, Stephen P. Thomas*, and Guy C. Lloyd-Jones* J. Am. Chem. Soc., 141, 18600–18611, 2019 Highlighted in JACS Spotlights "New Study Reveals Kinetics and Mechanism of Catalyzed Alkyne Hydroboration"
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159. Kinetic analysis of bioorthogonal reaction mechanisms using Raman microscopy William J. Tipping, Martin Lee, Valerie G. Brunton, Guy C. Lloyd-Jones and Alison N. Hulme* Faraday Discuss., 220, 71–85, 2019
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158. Gold-Catalyzed Oxidative Coupling of Arenes and Arylsilanes Chris Nottingham, Verity Barber, and Guy C. Lloyd-Jones* Organic Syntheses, 96, 150–178, 2019
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157. Kinetics of Initiation of the Third Generation Grubbs Metathesis Catalyst: Convergent Associative and Dissociative Pathways Veronica Forcina, Andres Garcia-Dominguez, and Guy C. Lloyd-Jones* Faraday Discussions, 220, 179–195, 2019
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156. Taming Ambident Triazole Anions: Regioselective Ion-Pairing Catalyzes Direct N-Alkylation with Atypical Regioselectivity Harvey J. A. Dale, George R. Hodges, and Guy C. Lloyd-Jones* J. Am. Chem. Soc., 141, 7181–7193, 2019
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155. Dehydropolymerization of H3B·NMeH2 using a [Rh(DPEphos)]+ catalyst: The promoting effect of NMeH2 Gemma Adams, David Ryan, Nicholas Beattie, Alasdair McKay, Guy Lloyd-Jones and Andrew Weller* ACS Catal., 9, 3657–3666, 2019
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154. Trimethylsilyldiazo[13C]methane: A Versatile 13C-Labelling Reagent Chris Nottingham and Guy C. Lloyd-Jones* Org. Synth., 95, 374-402, 2018
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153. Anion-Initiated Trifluoromethylation by TMSCF3: Deconvolution of the Siliconate-Carbanion Dichotomy by Stopped-Flow NMR/IR Craig P. Johnston, Thomas H. West, Ruth E. Dooley, Marc Reid, Ariana B. Jones, Edward J. King, Andrew G. Leach, and Guy C. Lloyd-Jones* J. Am. Chem. Soc., 140, 11112-11124, 2018
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152. Analysis of Auto-induction, Inhibition and Auto-Inhibition in a Rh-Catalyzed C-C Cleavage: Mechanism of Decyanative Aryl-Silylation Eric C. Keske, Thomas H. West, and Guy C. Lloyd-Jones* ACS Catalysis, 8, 8932–8940, 2018
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151. Au-Catalyzed Oxidative Arylation: Chelation-Induced Turnover of ortho-Substituted Arylsilanes Matthew P. Robinson and Guy C. Lloyd-Jones* ACS Catalysis, 8, 7484–7488, 2018
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150. Earth-Abundant Mixed-Metal Catalysts for Hydrocarbon Oxygenation James R. Pankhurst, Massimiliano Curcio, Stephen Sproules,* Guy C. Lloyd-Jones,* and Jason B. Love* Inorg. Chem., 57, 5915–5928, 2018
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149. The Dehydropolymerization of H3B·NMeH2 to form Polyaminoboranes using [Rh(Xantphos–alkyl)] Catalysts Gemma M. Adams, Annie L. Colebatch, Joseph T. Skornia, Alasdair I. McKay, Heather C. Johnson, Guy C. Lloyd–Jones, Stuart A. Macgregor, Nicholas A. Beattie, and Andrew S. Weller* J. Am. Chem. Soc., 140, 1481-1495, 2018
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148. Base-catalyzed Aryl-B(OH)2 Protodeboronation Revisited: from Concerted Proton-Transfer to Liberation of a Transient Arylanion Paul A. Cox, Marc Reid, Andrew G. Leach, Andrew D. Campbell, Edward J. King, and Guy C. Lloyd-Jones* J. Am. Chem. Soc., 139, 13156–13165, 2017
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147. SHARPER reaction monitoring: generation of a narrow line- width NMR singlet, without X-pulses, in an inhomogeneous magnetic field Ariana B. Jones, Guy C. Lloyd-Jones* and Dusan Uhrin* Analytical Chemistry, 89, 10013–10021, 2017
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146. Gold-Triggered Uncaging Chemistry in Living Systems Ana M. Pérez-López, Belén Rubio-Ruiz, Víctor Sebastián, Lloyd Hamilton, Catherine Adam, Thomas L. Bray, Silvia Irusta, Paul M. Brennan, Guy C. Lloyd-Jones, Dirk Sieger, Jesús Santamaría,* and Asier Unciti-Broceta* Angew. Chem. Int. Ed., 56, 12548–12552, 2017
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145. Catalytic Enantioselective [2,3]-Rearrangements of Allylic Ammonium Ylides: A Mechanistic and Computational Study Thomas H. West, Daniel M. Walden, James E. Taylor, Alexander C. Brueckner, Ryne C. Johnston, Paul Ha-Yeon Cheong,* Guy C. Lloyd-Jones* and Andrew D. Smith* J. Am. Chem. Soc., 139, 4366–4375, 2017
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144. Au-catalyzed Biaryl Coupling to Generate 5- to 9-membered Rings: Turnover-Limiting Reductive Elimination versus π-complexation Tom J. A. Corrie, Liam T. Ball, Christopher J. Russell and Guy C. Lloyd-Jones* J. Am. Chem. Soc., 139, 245–254, 2017
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143. Chemoselective oxidation of aryl organoboron systems enabled by boronic acid-selective phase transfer John J. Molloy, Thomas A. Clohessy, Craig Irving, Niall A. Anderson, Guy C. Lloyd-Jones and Allan J. B. Watson* Chem. Sci., 8, 1551-1559, 2017
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142. Formal Synthesis of (±)-Allocolchicine via Gold-Catalysed Direct Arylation: Implication of Aryl Iodine(III) Oxidant in Catalyst Deactivation Pathways Tom J. A. Corrie and Guy C. Lloyd-Jones* Topics in Catalysis, 60, 570-579, 2017
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141. Direct Measurements of Unimolecular and Bimolecular Reaction Kinetics of the Criegee Intermediate (CH3)2COO Rabi Chhantyal-Pun, Oliver Welz, John D. Savee, Arkke J. Eskola, Edmond P. F. Lee, Lucy Blacker, Henry R. Hill, Matilda Ashcroft, M Anwar H H. Khan, Guy C. Lloyd-Jones, Louise A Evans, Brandon Rotavera, Haifeng Huang, David L. Osborn, Daniel K.W. Mok, John M. Dyke, Dudley E. Shallcross, Carl J. Percival, Andrew J. Orr-Ewing* and Craig A. Taatjes* J. Phys. Chem. A, 121, 4–15, 2017
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140. Chiral Perylene Materials by Ionic Self-Assembly Geraldine Echue, Ian Hamley, Guy C. Lloyd-Jones and Charl F. J. Faul*
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139. Protodeboronation of heteroaromatic, vinyl and cyclopropyl boronic acids: pH-rate profiles, auto-catalysis and disproportionation Paul A. Cox, Andrew G Leach, Andrew D. Campbell and Guy C. Lloyd-Jones* J. Am. Chem. Soc., 138, 9145–9157, 2016 Highlighted in JACS Spotlights "Untangling Aqueous Instability of Organoboronic Acids"
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138. MIDA boronates are hydrolysed fast and slow by two different mechanisms Jorge A. Gonzalez, O. Maduka Ogba, Gregory F. Morehouse, Nicholas Rosson, Kendall N. Houk, Andrew G. Leach, Paul H.-Y. Cheong,* Martin D. Burke,* and Guy C. Lloyd-Jones* Nature Chem., 8, 1067–1075, 2016 Highlighted in PhysOrg "MIDA boronates react via two different mechanisms"
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137. Room Temperature Gold-Catalysed Arylation of Heteroarenes: Complementarity to Palladium Catalysis Alexander J. Cresswell and Guy C. Lloyd-Jones* |
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136. O-Phenylisourea Synthesis and Deprotonation: Carbodiimide Elimination Precludes the Reported Chapman Rearrangement Joseph A. Tate, George Hodges, and Guy C. Lloyd-Jones* |
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135. Pd-eta-3-C6H9 Complexes of the Trost Modular Ligand: High Nuclearity Columnar Aggregation Controlled by Concentration, Solvent and Counterion Daugirdas Tomas Racys, Julian Eastoe, Per-Ola Norrby, Isabelle Grillo, Sarah E. Rogers and Guy C. Lloyd-Jones* |
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134. Catalytic Amine Oxidation under Ambient Aerobic Conditions: Mimicry of Monoamine Oxidase B Alexander T. Murray, Myles J. H. Dowley, Fabienne Pradaux-Caggiano, Amgalanbaatar Baldansuren, Alistair J. Fielding, Floriana Tuna, Christopher H. Hendon, Aron Walsh, Guy C. Lloyd-Jones, Matthew P. John, and David R. Carbery* |
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133. Mechanism of Phosphine Borane Deprotection with Amines: the Effects of Phosphine, Solvent and Amine on Rate and Efficiency Guy C Lloyd-Jones* and Nicholas P. Taylor Chem. Eur. J., 21 ,5423-5428, 2015 *Hot Paper* |
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132. Chiral Perylene Diimides: Building Blocks for Ionic Self-Assembly Geraldine Echue, Guy C. Lloyd-Jones and Charl F. J. Faul* |
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131. Mechanistic Studies of the Dehydrocoupling and Dehydropolymerization of Amine–Boranes Using a [Rh(Xantphos)] Catalyst Heather C. Johnson, Erin M. Leitao, George R. Whittel, Ian Manners*, Guy C. Lloyd-Jones* and Andrew S. Weller* |
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130. Self-control tames the coupling of reactive radicals Guy C. Lloyd-Jones* and Liam T. Ball |
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129. Gold-Catalyzed Oxidative Coupling of Arylsilanes and Arenes: Origin of Selectivity and Improved Precatalyst Liam T. Ball, Guy C. Lloyd-Jones* and Christopher A. Russell* J. Am. Chem. Soc. ,136, 254–264, 2014. Highlighted in JACS Spotlights "Decipher the Code of Gold" |
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128. Selection of Boron Reagents in Suzuki-Miyaura coupling Alastair J. J. Lennox and Guy C. Lloyd-Jones* |
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127. Boron Reagent Activation in Suzuki-Miyaura Coupling Alastair J. J. Lennox and Guy C. Lloyd-Jones* Chapter in “Modern Cross Coupling: Evolution and Application” Edited by Thomas Colacot, RSC, 2014 |
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126. Quantum Yields for Photochemical Production of NO2 from Organic Nitrates at Tropospheric Wavelengths Christina Higgins,Louise Evans, Guy Lloyd-Jones, Dudley Shallcross, David Tew, and Andrew Orr-Ewing* |
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125.Diverse and potentially manipulative signalling with ascarosides in the model nematode C. elegant Anaid Diaz, Vincent Brunet, Guy C. Lloyd-Jones, William Spinner, Barney Wharam and Mark E Viney |
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124. Mechanisms of the Thermal and Catalytic Redistributions, Oligomerizations, and Polymerizations of Linear Diborazanes Alasdair P. M. Robertson, Erin M. Leitao, Titel Jurca, Mairi F. Haddow, Holger Helten,* |
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123. Transmetallation in Suzuki-Miyaura Coupling: The Fork in the Trail Alastair J. J. Lennox and Guy C. Lloyd-Jones* |
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122. Dehydrocoupling of Dimethylamine Borane Catalyzed by Rh(PCy3)2H2Cl Laura J. Sewell, Miguel A. Huertos, Molly E. Dickinson, Andrew S. Weller* and Guy C Lloyd-Jones |
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121. Paramagnetic Ti(III) and Zr(III) Metallocene Complexes as Precatalysts for the Dehydrocoupling/Dehydrogenation of Amine-Boranes, H. Helten, D. Barnali, J. Vance, M. Sloan, M. Haddow, D. Collison, S. Sproules, G. Whittell, G. C. Lloyd-Jones, and I. Manners* Angew. Chem. Int. Ed. 52, 437-440, 2013. Chosen by the referees as a Very Important Paper (VIP). |
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120. Gold-Catalyzed Direct Arylation Liam T Ball, Guy C Lloyd-Jones* and Christopher A. Russell* Science, 337, 1644-1648, 2012. Highlighted in Chemical and Engineering News: ' Biaryls Spun From Gold'. |
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119. The Mechanism of Metal-Free Hydrogen Transfer Between Amine-boranes and Aminoboranes E. Leitao, N. Stubbs, A. Robertson, H. Helten, R. J. Cox, G. C. Lloyd-Jones,* and I. Manners* |
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118. Preparation of Organotrifluoroborate Salts: Precipitation-driven Equilibrium under Non-Etching Conditions Alastair J. J. Lennox and Guy C. Lloyd-Jones* Angew. Chem. Int. Ed., 51, 9385-9388, 2012. Chosen by the referees as a Very Important Paper (VIP). Highlighted in RSC Chemistry World News: ' Fluoroborates without the etch'. |
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117. Expansion of the Ligand Knowledge Base for C helating P,P-Donor Ligands (LKB-PP) J. Jover, N. Fey,* J. N. Harvey, G. C. Lloyd-Jones, A. G. Orpen, G J. J. Owen-Smith, P. Murray, D. R. J. Hose, R. Osborne, and M. Purdie |
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116. Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate that Precedes Reductive Elimination R. Pawley, M. Huertos, G. C. Lloyd-Jones, A. S. Weller,* and M. Willis |
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115. Organotrifluoroborate Hydrolysis: Boronic Acid Release Mechanism and an Acid-Base Paradox in Cross-Coupling Alastair J. J. Lennox and Guy C. Lloyd-Jones* J. Am. Chem. Soc., 134, 7431-7441, 2012. Highlighted in RSC Chemistry World News: ' Keep stirring that Suzuki'. |
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114. Development of a generic mechanism for the dehydrocoupling of amine–boranes: a stoichiometric, catalytic and kinetic study of H3B·NMe2H using the [Rh(PCy3)2]+ fragment Laura J. Sewell, Guy C. Lloyd-Jones* and Andrew S Weller* |
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113. Pd-Catalyzed Reaction of Allyl Carbonate with Polyols: the Role of CO2 in Transesterification versus Etherification of Glycerol Alvaro Gordillo and Guy C. Lloyd-Jones* |
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112. Switching Pathways: Room Temperature Neutral Solvolysis and Substitution of Amides Marc Hutchby, Chris E. Houlden, Mairi F. Haddow, Simon N. G. Tyler, Guy C. Lloyd-Jones,* and Kevin I. Booker-Milburn* Angew. Chem. Int. Ed., 51, 548-551, 2012. Highlighted in Chemical and Engineering News: ' New Twist On Amide Activation'. |
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111. Gold-Catalysed Oxyarylation of Styrenes, Mono- and gem-Disubstituted Olefins Facilitated by an Iodine(III) Oxidant Liam T. Ball, Guy C. Lloyd-Jones* and Christopher A. Russell* |
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110. The Even-Handed Approach: Strategies for the Deployment of Racemic Chiral Catalysts Louise A. Evans, Neil S. Hodnett and Guy C. Lloyd-Jones* |
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103. 'The Slow-Release Strategy in Suzuki-Miyaura Coupling'; Invited contribution to Special Issue on Cross-Coupling & Nobel Prize in Chemistry Alastair J. J. Lennox and Guy C. Lloyd-Jones |
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102. Expansion of the Ligand Knowledge Base for Monodentate P-Donor Ligands (LKB-P) Jesús Jover, Natalie Fey,* Jeremy N. Harvey, Guy C. Lloyd-Jones, A. Guy Orpen and Gareth J. J. Owen-Smith |
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101. Arylsilanes: Application to Gold-Catalyzed Oxyarylation of Alkenes Liam Ball, Michael Green, Guy C. Lloyd-Jones,* and Christopher Russell* Org. Lett., 12, 4724–4727, 2010. Highlighted in Synfacts (2011, 1, 76) |
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100. The Molecularity of the Newman Kwart Rearrangement Matthew Burns, Guy C. Lloyd-Jones*, Jonathan D. Moseley, and Joseph S. Renny J. Org. Chem., 75, 6347-6353, 2010. Selected by the Editor as a Featured Article. |
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99. Electrospray Mass Spectrometric Studies of Two Palladium-Allyl Complexes of the Trost Standard Ligand Divya Agrawal, Detlef Schroeder*, David A. Sale and Guy C. Lloyd-Jones* |
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98. A Simple and Effective Co-Catalyst for Ring-Closing Enyne-Metathesis Using Grubbs I type Catalysts: A Practical Alternative to "Mori's Conditions" Guy C. Lloyd-Jones,* Alan J. Robinson, Laurent Lefort and Johannes G. de Vries Chosen by the referees as a Very Important Paper (VIP) |
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97. Facile Double-Lithiation of a Transient Urea: Vicarious ortho-metallation of Aniline Derivatives C. E. Houlden, G. C. Lloyd-Jones,* K. I Booker-Milburn* |
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96. Aryl Trifluoroborates in Suzuki-Miyaura Coupling: The Roles of Endogenous Aryl Boronic Acid and Fluoride Mike Butters, Jeremy N. Harvey, Jesús Jover, Alastair J. J. Lennox, Guy C. Lloyd-Jones,* and Paul M. Murray Angew. Chem. Int. Ed., 49, 5156-5160, 2010. Chosen by the editors as a Hot Paper. Highlighted in Chemical and Engineering News: 'Mechanism Of Suzuki-Miyaura Coupling Revealed'. |
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95. Memory and dynamics in Pd-catalyzed allylic alkylation with PN-ligands Charlotte Johansson, Guy C. Lloyd-Jones, Per-Ola Norrby* Tetrahedron: Asymmetry (Special Issue in honour of Henri Kagan), 21, 1585-1592, 2010. |
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94. Can π6 + π4 = 10? Exploring cycloaddition routes to highly unsaturated 10-membered rings Roger W. Alder*, Guy C. Lloyd-Jones, Jeremy N. Harvey, Josep Oliva |
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93. A Computational Study of Phosphine Ligand Effects in Suzuki-Miyaura Coupling Jesús Jover, Natalie Fey, Mark Purdie, Guy C Lloyd-Jones, Jeremy N. Harvey* |
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92. Homogeneous Catalytic Dehydrocoupling/Dehydrogenation of Amine-Borane Adducts by Early Transition Metal, Group 4 Metallocene Complexes M. Sloan, A. Staubitz, T. Clark, C. Russell, G. C. Lloyd-Jones* and I. Manners* |
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91. The use of reactive tracers to determine ambient OH radical concentrations: application within the indoor environment I. R. White, D. Martin, M. Paz Muñoz, F. K. Petersson, S. J. Henshaw, G. Nickless, G. C. Lloyd-Jones, K. C. Clemitshaw and D. E. Shallcross* Environmental Science & Technology, 44, 6269-6274, 2010. Highlighted in Chemical and Engineering News: 'To Track an Oxidant'. |
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90. Interrogation of a Dynamic Multi-catalyst Ensemble in Asymmetric Catalysis Julian Eastoe, Ian J. S. Fairlamb, Jesus M. Fernandez-Hernandez, Emane Filali, John C. Jeffery, Guy C. Lloyd-Jones,* Aina Martorell, Antony Meadowcroft, Per-Ola Norrby, Thomas Riis-Johannessen, David A. Sale and Paula M. Tomlin |
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89. Hindered Ureas as Masked Isocyanates: Facile Carbamoylation of Nucleophiles under Neutral Conditions M. Hutchby, C. E. Houlden, J. G. Ford, S. N. G. Tyler, M. R. Gagné, G. C. Lloyd-Jones* and K. I. Booker- Milburn* Angew. Chem. Int. Ed., 48, 8721-8724, 2009. Chosen by the editors as a Hot Paper. |
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88. The Newman-Kwart Rearrangement of O-aryl thiocarbamates: Dramatic Reduction in Reaction Temperatures via Pd Catalysis J. N. Harvey, J. Jover, G. C. Lloyd-Jones*, J. D. Moseley, P. Murray and J. S. Renny Angew. Chem. Int. Ed., 48, 7612-7615, 2009. Highlighted in Synfacts (2010) 1, 87-87. |
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87. A Structure-Based Rationale for selectivity in the Asymmetric Allylic Alkylation of Cyclohexenyl Esters Employing the Trost 'Standard Ligand' (TSL): Isolation, Analysis and Alkylation of the Monomeric Form of the Cationic η3-Cyclohexenyl Complex [(η3-c-C6H9)Pd(TSL)]+ Craig P. Butts, Emane Filali, Guy C. Lloyd-Jones*, Per-Ola Norrby*, David A. Sale and York Schramm J. Am. Chem. Soc., 131, 9945-9957, 2009. Highlighted in Chemical and Engineering News, 2009, vol. 87 (Issue 42), pp 31-33: 'A Tale of Two Catalysts'. |
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86. Cryptocatalytic 1,2-Alkene Migration in a σ-Alkyl Palladium Diene Complex Louise A. Evans, Natalie Fey, Guy C. Lloyd-Jones*, M. Paz Muñoz, and Paul A. Slatford |
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85. Room Temperature Pd-catalyzed C—H Activation: ortho-Carbonylation of Aniline Derivatives Chris E. Houlden, Marc Hutchby, Chris D. Bailey, J. Gair Ford, Simon N. G. Tyler, Michel R. Gagné, Guy C. Lloyd-Jones* and Kevin I. Booker- Milburn* Angew. Chem. Int. Ed., 48, 1830–1833, 2009. Chosen by the editors as a Hot Paper. |
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84. Triflic Acid Mediated Dealkylative Lactonisation via NMR-Observable Alkyl Oxonium Intermediates M. Paz Muñoz* and Guy C. Lloyd-Jones |
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83. Cleavage of tert-Butyl Benzoates with NaH in DMF. Comments on the Mechanism and a Simple and Safe Alternative Procedure Emane Filali, Guy C. Lloyd-Jones* and David A. Sale |
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82. Counterintuitive Kinetics in Tsuji-Trost Allylation: Ion-pair Partitioning and Implications for Asymmetric Catalysis Louise A. Evans, Natalie Fey, Jeremy N. Harvey, David Hose, Guy C. Lloyd-Jones,* Paul Murray, A. Guy Orpen, Robert Osborne, Gareth J. J. Owen-Smith, and Mark Purdie J. Am. Chem. Soc., 130, 14471–14473, 2008. Highlighted in Synfacts, 3, 292-292, 2009. |
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81. A New Class of 3′-Sulfonyl BINAPHOS Ligands: Modulation of Activity and Selectivity in Asymmetric Pd-Catalysed Hydrophosphorylation of Styrene Katalin Barta, Giancarlo Francio, Walter Leitner,* Guy C. Lloyd-Jones,* and Ian Shepperson |
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80. Distinct Reactivity of Pd(OTs)2: the Intermolecular Pd(II)-Catalyzed 1,2-Carboamination of Dienes Christopher Houlden, Christopher Bailey, Gair Ford, Michel Gagné, Guy C Lloyd-Jones,* and Kevin I. Booker-Milburn* J. Am. Chem. Soc., 130, 10066–10067, 2008. Highlighted in Synfacts, 10, 1088-1088, 2008. |
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79. BINOL-3,3′-Triflone N-Methyl Phosphoramidites: Through-Space 19F,31P Spin-Spin Coupling with a Remarkable Dependency on Temperature and Solvent Internal Pressure Matthias Kruck, M. Paz Muñoz, Hannah L. Bishop, Christopher G. Frost, Christopher J. Chapman, Gabriele Kociok-Köhn, Craig P. Butts* and Guy C. Lloyd-Jones* |
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78. Decoupling Deprotonation from Metallation: thia-Fries rearrangement Alan M. Dyke, Duncan M. Gill, Jeremy N. Harvey, Alison J. Hester, Guy C. Lloyd-Jones*, M. Paz Muñoz and Ian R. Shepperson |
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77. Computational Descriptors for Chelating P,P- and P,N-Donor Ligands Natalie Fey*, Jeremey N. Harvey*, Guy C. Lloyd-Jones, Paul Murray, A Guy Orpen*, Robert Osborne and Mark Purdie |
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76. Mechanism and Application of the Newman-Kwart O→S rearrangement of O-Arylthiocarbamates Guy C. Lloyd-Jones,* Jonathan D. Moseley and Joseph S. Renny |
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75. Mechanism of Methyl-Esterification of Carboxylic Acids by Trimethylsilyl-diazomethane Erik Kühnel, David D. P. Laffan, Guy C. Lloyd-Jones,* Teresa Martínez del Campo, Ian R. Shepperson and Jennifer L. Slaughter |
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74. A Chemo- and Regio-Selective Three-Component Dihydropyrimidinone Synthesis Chris D. Bailey, Chris E. Houlden, Grégory L. J. Bar, Guy C. Lloyd-Jones and Kevin I. Booker-Milburn* |
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73. Isotopic Labelling in the Study of Organic and Organometallic Mechanism and Structure: An Account Guy C. Lloyd-Jones* and M. Paz Muñoz Invited contribution to the 50th Anniversary Special Issue of the Journal of Labelled Compounds and Radiopharmaceuticals, 50, 1072-1082, 2007 |
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72. Readily Accessible, Modular and Tuneable BINOL 3,3′-Perfluoroalkylsulfones: Highly Efficient Catalysts for Enantioselective In-Mediated Imine Allylation Robert Kargbo, Yoko Takahashi, Santosh Bhor, Gregory R. Cook,* Guy C. Lloyd-Jones,* and Ian R. Shepperson |
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71. Intermolecular Chirality Transfer from Silicon to Carbon: Interrogation of the Two- Silicon Cycle for Pd-Catalyzed Hydrosilylation by Stereoisotopochemical Cross-over Sebastian Rendler, Martin Oestreich,* Craig P. Butts, and Guy C. Lloyd-Jones* |
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70. Mechanism of Cycloisomerisation of 1,6-Heptadienes Catalysed by (tBuCN)2PdCl2: Remarkable Influence of Exogenous and Endogenous 1,6- and 1,5-Diene Ligands Katharine L. Bray, Guy C. Lloyd-Jones,* M. Paz Muñoz, Paul A. Slatford, Emily H. P. Tan, Amanda R. Tyler-Mahon and Paul A. Worthington |
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69. Review: Organometallic Generation and Capture of ortho-Arynes Alan M Dyke, Alison J. Hester and Guy C. Lloyd-Jones* |
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68. Highlight: The remarkable crossed co-isomerisation reaction of cyclopropyl ketones and enones via nickeladihydropyrans Guy C. Lloyd-Jones |
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67. Mechanistic Implications of Pseudo Zero Order Kinetics in Kinetic Resolutions Donna G. Blackmond,* Neil S. Hodnett and Guy C. Lloyd-Jones* |
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66. Enantioselective Homoallyl-cyclopropanation of Dibenzylideneacetone by Modified Allylindium Halide Reagents: Rapid Access to Enantioenriched 1-Styryl-Norcarene Guy C. Lloyd-Jones*, Philip D. Wall, Jennifer L. Slaughter, Alexandra J. Parker and David P. Laffan Prof. D. W. MacMillan Special Issue - Tetrahedron, invited submission, 62, 11402-11412, 2006 |
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65. Intermolecular Insertion of an N,N-Heterocyclic Carbene into a Nonacidic C-H bond: Kinetics, Mechanism and Catalysis by (K-HMDS)2 Roger W. Alder, Guy C. Lloyd-Jones* and Gareth J. J. Owen-Smith |
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64. Asymmetric Allylic Substitution Catalyzed by C1-Symmetrical Complexes of Molybdenum: Structural Requirements of the Ligand and the Stereochemical Course of the Reaction Andrei V. Malkov,* Laure Gouriou, Guy C. Lloyd-Jones,* Ivo Starý, Vratislav Langer, Paul Spoor, Victoria Vinader, and Pavel Kocovský* |
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63. On the Stability of the π-Allyl Intermediate in Molybdenum-Catalyzed Asymmetric Alkylations Jennifer A. R. Luft, Zhi-Xiang Yu, David Hughes, Guy C. Lloyd-Jones, Shane W. Krska, K. N. Houk Prof. J. Halpern Special Issue - Tetrahedron: Asymmetry, 17, 716-724, 2006 |
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62. Catalysis by Organometallic Compounds Guy C. Lloyd-Jones Chapter in "The Investigation of Organic Reaction Mechanisms" Edited by H. Maskill, Blackwell, Oxford, 2006 |
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61. Rate Enhancement by Ethylene in Ru-catalysed Ring-closing Metathesis of Enynes: Evidence for an "Ene-then-yne" Pathway that Diverts through a Second Catalytic Cycle Guy C. Lloyd-Jones*, Robert G. Margue and Johannes G. de Vries Angew. Chem. Int. Ed., 44, 7442–7447, 2005 Chosen by the referees as a Very Important Paper (VIP) |
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60. Pd(II) Catalysed Intermolecular 1,2-Diamination of Dienes Grégory L. J. Bar, Guy C. Lloyd-Jones* and Kevin I. Booker-Milburn* |
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59. Re-evaluation of the Mechanism of the Baylis-Hillman Reaction: Implications for Asymmetric Catalysis Varinder K. Aggarwal*, Sarah Y. Fulford and Guy C. Lloyd-Jones* |
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51. 2H-Quadrupolar Coupling-based Analysis of Stereochemical and Regiochemical Memory in the Pd-catalysed Allylic Alkylation of iso-Cinnamyl type Substrates Employing the Chiral Monophosphine Ligands 'MOP' and 'MAP' Laure Gouriou, Guy C. Lloyd-Jones,* Stepan Vyskocil and Pavel Kocovský |
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50. Scalar coupling between the 15N centres in methylated 1,8-diaminonaphthalenes and 1,6-diazacyclodecane: to what extent is 2HJNN a reliable indicator of N-N distance? Guy C. Lloyd-Jones,* Jeremy N. Harvey*, Paul Hodgson, Martin Murray and Robert L. Woodward |
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49. Highlights from the 38th ESF/EUCHEM Conference on Stereochemistry, Bürgenstock, Switzerland, April/May 2003 Mathew Gaunt and Guy C. Lloyd-Jones |
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48. Modification of the Atropisomeric N,N-Ligand 2,2′-bis(Pyridin-2-yl)-1,1′-binaphthalene and its Application to the Asymmetric Allylation of Benzaldehyde Jonathan P. H. Charmant, Neil J. Hunt, Guy C. Lloyd-Jones* and Thorsten Nowak |
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47. The Anionic Thia-Fries Rearrangement of Aryl Triflates Jonathan P. H. Charmant, Alan M. Dyke and Guy C. Lloyd-Jones* |
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46. Mechanistic Aspects of Transition Metal Catalysed 1,6-Diene and 1,6-Enyne Cycloisomerisation Reactions Guy C. Lloyd-Jones |
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45. Analysis of Stereochemical Convergence in Asymmetric Pd-Catalysed Allylic Alkylation Reactions Complicated by Halide and Memory Effects Ian J. S. Fairlamb, Guy C. Lloyd-Jones*, Stephan Vyskocil and Pavel Kocovský |
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44. Highlight: Palladium-catalysed α-Arylation of Esters: Ideal New Methodology for Discovery Chemistry Guy C. Lloyd-Jones |
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43. Convenient, Rapid and Highly Regioselective Cycloisomerisation of 4,4-Disubstituted Hepta-1,6-dienes Employing Neutral Palladium-Chloride pro-Catalysts Katharine L. Bray, Ian J. S. Fairlamb, Jan-Phillip Kaiser, Guy C. Lloyd-Jones* and Paul A. Slatford |
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42. Testing Racemic Chiral Catalysts for Kinetic Resolution Potential Beatriz Dominguez, Neil S. Hodnett, Guy C. Lloyd-Jones* |
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41. Organometallic chemistry. Part (ii) Transition metals in organic synthesis–stoichiometric applications Beatriz Dominguez, Neil S. Hodnett, Guy C. Lloyd-Jones* Annu. Rep. Prog. Chem., Sect. B: Org. Chem., 97, 113-141, 2001 |
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40. Structural and Mechanistic Studies of the Activation and Propagation of a Cationic Allyl-Pd pro-catalyst in 1,6-diene Cycloisomerisation Katharine L. Bray, Ian J. S. Fairlamb, Jonathan P. H. Charmant, Guy C. Lloyd-Jones* |
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39. Halide redistribution in Pd-catalysed 1,6-diene cycloisomerisation Katharine L. Bray, Ian J. S. Fairlamb, Guy C. Lloyd-Jones* Highlighted in Chemistry and Industry, 2001, 316-317 |
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38. Synthesis of [2H, 13C]-labelled Diallylmalonates - Useful Probes for the Study of Transition Metal catalysed 1,6-diene Cycloisomerisation Katharine L. Bray, Guy C. Lloyd-Jones* |
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37. On the Evidence for Formation of an exo-π-Allyl Complex Intermediate in the Pd0-Catalysed Alkylation of a Bicyclic Allylic Diacetate Guy C. Lloyd-Jones |
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36. Isotopic Desymmetrisation as a Stereochemical Probe Guy C. Lloyd-Jones |
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35. Entropy-Driven Hydrogen Bonding: Stereodynamics of a Protonated, N,N-Chiral "Proton Sponge" Paul Hodgson, Guy C. Lloyd-Jones*, Martin Murray, Torren M. Peakman and Robert L. Woodward |
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34. On the effect of catalyst loading in Pd-catalysed allylic alkylation Ian J. S. Fairlamb and Guy C. Lloyd-Jones* |
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33. Organometallic chemistry. Part (ii) Transition metals in organic synthesis–stoichiometric applications Guy C. Lloyd-Jones |
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32. Diastereoisomeric Cationic π-allyl-Pd-(P,C)-MAP and MOP Complexes and their Relationshipto Stereochemical Memory Effects in Allylic Alkylation Guy C. Lloyd-Jones*, Susanna C. Stephen, Martin Murray, Craig P. Butts, Stepan Vyskocil* and Pavel Kocovský* |
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31. Ligand Exchange and Stereodynamics in the Cationic Pd(II)-π-allyl Complex of 2,2′-bis(Pyridyl)-1,1′-binaphthalene, a Novel Atropisomeric N,N-Ligand Jonathan P. H. Charmant, Ian A. Fallis, Neil J. Hunt, Guy C. Lloyd-Jones*, Martin Murray and Thorsten Nowak |
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30. Powerful Kinetic Diastereoselection in Ruthenium-catalysed Ring-closing Methathesis of Homoallyl Vinyl Cyclopropanes Guy C. Lloyd-Jones*, Martin Murray, Rosie A. Stentiford and Paul A. Worthington |
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29. Highly Substituted Homoallylvinylcyclopropanes by Indium-Mediated Reaction of α,β-Unsaturated Ketones and Aldehydes with Allylic Halides Stephen M. Capps, Timothy P. Clarke, Henning A. F. Höppe, Guy C. Lloyd-Jones*, Martin Murray, Torren M. Peakman, Rosie A. Stentiford, Kenneth E. Walsh and Paul A. Worthington |
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28. Robust and Catalytically Active Mono- and Bis-Pd Complexes of the 'Trost Modular Ligand' Craig P. Butts, John Crosby, Guy C. Lloyd-Jones* and Susanna C. Stephen |
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27. Organometallic chemistry . Part (ii) Transition metals in organic synthesis – stoichiometric applications Guy C. Lloyd-Jones |
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26. Transition Metal Catalysis in Organic Syntheis: Reflections, Chirality, and New Vistas Pavel Kocovsky*, Andrei Malkov, Stepan Vyskocil and Guy C. Lloyd-Jones |
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25. Palladium(II) Complexes of 2-Dimethylamino-2′-diphenylphosphino-1,1′-binaphthyl (MAP) with Unique P,Cσ-Coordination and Their Catalytic Activity in Allylic Substitution, Hartwig–Buchwald Amination, and Suzuki Coupling Pavel Kocovsky*, Stepan Vyskocil*, Ivana Cisarova, Jan Srjbal, Iva Tislerova, Marticn Smrcina, Guy C. Lloyd-Jones*, Susanna C. Stephen, Craig P. Butts, Martin Murray and Vratislav Langer |
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24. Synthesis, Structure and Stereodynamics of an N,N-Chiral 'Proton Sponge' Jonathan P. H. Charmant, Guy C. Lloyd-Jones*, Torren M. Peakman and Robert L. Woodward |
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23. Stable Palladium Catalyst Guy C. Lloyd-Jones UK Patent application, 1999 |
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22. Chloride Ion Effects on Kinetic Resolution in Pd-Catalysed Allylic Substitution Guy C. Lloyd-Jones* and Susanna C. Stephen |
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21. Organometallic chemistry. Part (ii) Stoichiometric methods Guy C. Lloyd-Jones |
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20. Kinetic Diastereoselection of Homoallylic Indium Alkoxides: Syn Crotylation of Arylaldehydes Guy C. Lloyd-Jones* and Tim Russell |
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19. Memory Effects in Pd-Catalysed Allylic Alkylation: Stereochemical Labelling Through Isotopic Desymmetrization Guy C. Lloyd-Jones* and Susanna C. Stephen |
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18. Synthesis of a Protonated C2-Symmetric N,N-Chiral "Proton Sponge" Jonathan P. H. Charmant, Guy C. Lloyd-Jones*, Torren M. Peakman and Robert L. Woodward |
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17. Perfect Complementarity in the Fitting of Two Homochiral Heterodonor Ligands Around a Nickel(II) Centre: an 'Intramolecular Embrace' Katherine L. Bray, Craig P. Butts, Guy C. Lloyd-Jones* and Martin Murray |
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16. Homoallyl-Substituted Vinylcyclopropanes from α,β-Unsaturated Ketones and Allylindium Derivatives (Homoallyl-substituierte Vinylcyclopropane aus α,β-ungesättigten Ketonen und Allylindium-Derivaten) Henning A. F. Höppe, Guy C. Lloyd-Jones*, Martin Murray, Torren M. Peakman and Kenneth E. Walsh Angew. Chem., 110, 1653-1655, 1998 |
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15. Regioselectivity and Diastereoselectivity in the Indium-mediated Homoallyl-Cyclopropanation of Dibenzylidene Acetone (dba) Steven M. Capps, Torren M. Peakman, Guy C. Lloyd-Jones,* Martin Murray and Kenneth E. Walsh |
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14. Nickel(II) Complexes Bearing Phosphinoaryl Oxazoline Ligands as Pro-catalysts for Grignard Cross-Coupling Guy C. Lloyd-Jones* and Craig P. Butts |
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13. Regiocontrol and Stereoselectivity in Tungsten-Bypridine Catalysed Allylic Alkylation Jürg Lehmann and Guy C. Lloyd-Jones* |
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12. Enantio- and Regiocontrol in Palladium- and Tungsten-Catalyzed Allylic Substitutions Roger Prétôt, Guy. C. Lloyd-Jones and Andreas Pfaltz* |
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11. Enantioselective Allylic Substitution Catalyzed by Chiral Bisoxazoline Pd Complexes: Catalyst Structure and Possible Mechanism of Enantioselection Peter von Matt, Guy C. Lloyd-Jones, Alexander B. E. Minidis, Andreas Pfaltz*, Ludwig Macko, Markus Neuburger, Margareta Zehnder, Heinz Rüegger and Paul S. Pregosin* |
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10. Synthesis of Chiral Phosphinoaryl oxazolines, a Versatile Class of Ligands for Asymmetric Catalysis Guido Koch, Guy. C. Lloyd-Jones, Olivier Loiseleur, Andreas Pfaltz*, Roger Prétôt, Silvia Schaffner, Patrick Schneider and Peter von Matt Recl. Trav. Chim. Pay-Bas, 114, 206–210, 1995 |
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9. Synthesis and Structures of Low-Valent Tungsten Complexes Bearing Chiral Oxazoline-Derived Ligands Guy. C. Lloyd-Jones and Andreas Pfaltz* Z. Naturforsch. B, 50, 361–367, 1995 |
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8. Chiral Phosphanodihydrooxazoles in Asymmetric Catalysis: Tungsten-Catalyzed Allylic Substitution Guy. C. Lloyd-Jones and Andreas Pfaltz* Angew. Chem., 107, 534–536, 1995 |
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7. Mechanism and Synthesis in Catalytic Hydroboration John M. Brown*, Henri Doucet, Elana Fernadez, H. Eric Heeres, Mark, W. Hooper, David I. Hulmes, Frances I. Knight. Timothy P. Layzell and Guy C. Lloyd-Jones Organometallics in Organic Synthesis, 'Chemistry in the 21st Century' series, Blackwell, Oxford, 1998 |
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6. Vinylborane Formation in Rhodium-Catalyzed Hydroboration of Vinylarenes. Mechanism versus Borane Structure and Relationship to Silation John M. Brown* and Guy C. Lloyd-Jones |
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5. Reversible Dimerisation of Ephedrine-derived Oxazaborolidines John M. Brown*, Guy C. Lloyd-Jones and Timothy. P. Layzel |
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4. Vinylborane Formation in Rhodium-catalysed Hydroborations; Ligand-free Homogeneous Catalysis John M. Brown*, Simon. W. Leppard and Guy C. Lloyd-Jones |
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3. A Rapid Assay for the Enantiomeric Purity of Secondary Alcohols using 4S,5R-4-methyl,5-phenyl-1,3,2-oxazaborolidine (Ephedrineborane) John M. Brown*, Simon. W. Leppard and Guy C. Lloyd-Jones |
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2. Control Factors for Selective Homogeneous Catalysis J. M. Brown*, J. V. Carey, A. D. Conn, G. C. Lloyd-Jones and S. C. Woodward Advances in Catalyst Design, World Scientific Press, Singapore, 1991 |
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1. Catalytic Asymmetric Hydroboration with Oxazaborolidines John M. Brown and Guy C. Lloyd-Jones |